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Versatile Heterogeneous Palladium Catalysts for Diverse Carbonylation Reactions under Atmospheric Carbon Monoxide Pressure
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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Number of Authors: 5
2018 (English)In: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 10, no 5, p. 1089-1095Article in journal (Refereed) Published
Abstract [en]

Herein, we report a versatile carbonylation protocol using heterogeneous Pd-0 nanoparticles supported on the metal-organic frameworks (MOFs) MIL-88B-NH2 (Fe/Cr). The synthesis of a vast array of carbonyls, which includes amides, esters, carboxylic acids, and -ketoamides, was achieved through mono- and dicarbonylation reactions. The selectivity could be controlled simply by tuning the reaction conditions. Superior activity and selectivity were recorded in some cases compared to that achieved with commercial Pd/C. However, the utility of an elaborate catalyst support is questionable and important reactivity and recyclability issues are discussed.

Place, publisher, year, edition, pages
2018. Vol. 10, no 5, p. 1089-1095
Keyword [en]
carbonylation, heterogeneous catalysis, metal-organic frameworks, nanoparticles, palladium
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-154727DOI: 10.1002/cctc.201701439ISI: 000426844600030OAI: oai:DiVA.org:su-154727DiVA, id: diva2:1195015
Available from: 2018-04-04 Created: 2018-04-04 Last updated: 2018-04-04Bibliographically approved

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González Miera, GrecoPascanu, VladInge, A. KenMartín‐Matute, Belén
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