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Dissociation kinetics of excited ions: PEPICO measurements of Os-3(CO)(12) - The 7-35 eV single ionization binding energy region
Stockholm University, Faculty of Science, Department of Physics.ORCID iD: 0000-0002-3863-9454
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
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Number of Authors: 7
2018 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 148, no 8, article id 084301Article in journal (Refereed) Published
Abstract [en]

In this article, we study the photoinduced dissociation pathways of a metallocarbonyl, Os-3(CO)(12), in particular the consecutive loss of CO groups. To do so, we performed photoelectron-photoion coincidence (PEPICO) measurements in the single ionization binding energy region from 7 to 35 eV using 45-eV photons. Zero-energy ion appearance energies for the dissociation steps were extracted by modeling the PEPICO data using the statistical adiabatic channel model. Upon ionization to the excited ionic states above 13 eV binding energy, non-statistical behaviorwas observed and assigned to prompt CO loss. Double ionization was found to be dominated by the knockout process with an onset of 20.9 similar to 0.4 eV. The oscillator strength is significantly larger for energies above 26.6 similar to 0.4 eV, corresponding to one electron being ejected from the Os3 center and one from the CO ligands. The cross section for double ionization was found to increase linearly up to 35 eV ionization energy, at which 40% of the generated ions are doubly charged.

Place, publisher, year, edition, pages
2018. Vol. 148, no 8, article id 084301
Keyword [en]
Materials, Atom photon interactions, Metals, Atomic and molecular physics, Condensed matter properties, Condensed matter physics, Metallurgy, Molecule photon interactions, Isomerization, Molecular spectra
National Category
Chemical Sciences Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-154841DOI: 10.1063/1.5018719ISI: 000426582700015PubMedID: 29495778OAI: oai:DiVA.org:su-154841DiVA, id: diva2:1196471
Available from: 2018-04-10 Created: 2018-04-10 Last updated: 2018-04-10Bibliographically approved

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