Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Two Aluminophosphate Molecular Sieves Built from Pairs of Enantiomeric Structural Building Units
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Show others and affiliations
Number of Authors: 62018 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 57, no 14, p. 3727-3732Article in journal (Refereed) Published
Abstract [en]

Herein we report the synthesis and structures of two new small-pore aluminophosphate molecular sieves PST-13 and PST-14 with mutually connected 8-ring channels. The structure of PST-13, synthesized using diethylamine as an organic structure-directing agent, contains penta-coordinated framework Al atoms bridged by hydroxy groups and thus edge-sharing 3- and 5-rings. Upon calcination, PST-13 undergoes a transformation to PST-14 with loss of bridging hydroxy groups and occluded organic species. The structures of both materials consist nonjointly of pairs of previously undiscovered 1,5- and 1,6-open double 4-rings (d4rs) which are mirror images of each other. We also present a series of novel chemically feasible hypothetical structures built from 1-open d4r (sti) or 1,3-open d4r (nsc) units, as well as from these two enantiomeric structural building units.

Place, publisher, year, edition, pages
2018. Vol. 57, no 14, p. 3727-3732
Keywords [en]
aluminophosphates, enantiomeric structural building units, microporous materials, structure elucidation, zeolites
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-156086DOI: 10.1002/anie.201800791ISI: 000428350100033PubMedID: 29504653OAI: oai:DiVA.org:su-156086DiVA, id: diva2:1207041
Available from: 2018-05-18 Created: 2018-05-18 Last updated: 2018-05-18Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Yang, TaiminZou, Xiaodong
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
Angewandte Chemie International Edition
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 14 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf