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Synthesis of Phenols and Aryl Silyl Ethers via Arylation of Complementary Hydroxide Surrogates
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2018 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 20, no 7, p. 1785-1788Article in journal (Refereed) Published
Abstract [en]

Two transition-metal-free methods to access substituted phenols via the arylation of silanols or hydrogen peroxide with diaryliodonium salts are presented. The complementary reactivity of the two nucleophiles allows synthesis of a broad range of phenols without competing aryne formation, as illustrated by the synthesis of the anesthetic Propofol. Furthermore, silyl-protected phenols can easily be obtained, which are suitable for further transformations.

Place, publisher, year, edition, pages
2018. Vol. 20, no 7, p. 1785-1788
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Chemical Sciences
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URN: urn:nbn:se:su:diva-155954DOI: 10.1021/acs.orglett.8b00287ISI: 000429886900022PubMedID: 29537280OAI: oai:DiVA.org:su-155954DiVA, id: diva2:1208816
Available from: 2018-05-21 Created: 2018-05-21 Last updated: 2018-06-29Bibliographically approved

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Available from 2019-03-14 01:00

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Reitti, MarcusGurubrahamam, RamaniLindstedt, ErikOlofsson, Berit
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