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Synthesis and Physical Properties of the Oxofluoride Cu-2(SeO3)F-2
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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Number of Authors: 82018 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 57, no 8, p. 4640-4648Article in journal (Refereed) Published
Abstract [en]

Single crystals of the new compound Cu-2(SeO3)F-2 were successfully synthesized via a hydrothermal method, and the crystal structure was determined from single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pnma with the unit cell parameters a = 7.066(4) (A) over circle, b = 9.590(4) (A) over circle, and c = 5.563(3) (A) over circle. Cu-2(SeO3)F-2 is isostructural with the previously described compounds Co2TeO3F2 and CoSeO3F2. The crystal structure comprises a framework of corner- and edge-sharing distorted [CuO3F3] octahedra, within which [SeO3] trigonal pyramids are present in voids and are connected to [CuO3F3] octahedra by corner sharing. The presence of a single local environment in both the F-19 and Se-77 solid-state MAS NMR spectra supports the hypothesis that O and F do not mix at the same crystallographic positions. Also the specific phonon modes observed with Raman scattering support the coordination around the cations. At high temperatures the magnetic susceptibility follows the Curie-Weiss law with Curie temperature of Theta = -173(2) K and an effective magnetic moment of mu(eff) similar to 2.2 mu(B). Antiferromagnetic ordering below similar to 44 K is indicated by a peak in the magnetic susceptibility. A second though smaller peak at similar to 16 K is tentatively ascribed to a magnetic reorientation transition. Both transitions are also confirmed by heat capacity measurements. Raman scattering experiments propose a structural phase instability in the temperature range 6-50 K based on phonon anomalies. Further changes in the Raman shift of modes at similar to 46 K and similar to 16 K arise from transitions of the magnetic lattice in accordance with the susceptibility and heat capacity measurements.

Place, publisher, year, edition, pages
2018. Vol. 57, no 8, p. 4640-4648
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Chemical Sciences
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URN: urn:nbn:se:su:diva-156734DOI: 10.1021/acs.inorgchem.8b00372ISI: 000430437400048PubMedID: 29613786OAI: oai:DiVA.org:su-156734DiVA, id: diva2:1220001
Available from: 2018-06-18 Created: 2018-06-18 Last updated: 2018-06-18Bibliographically approved

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Mitoudi-Vagourdi, EleniPapawassiliou, WassiliosJaworski, AleksanderPell, Andrew J.Johnsson, Mats
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Inorganic Chemistry
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