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Iterative Synthesis of Pluripotent Thioethers through Controlled Redox Fluctuation of Sulfur
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-9199-6736
Number of Authors: 22018 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, Vol. 29, no 10, p. 1329-1333Article in journal (Refereed) Published
Abstract [en]

Target- and diversity-oriented syntheses are based on diverse building blocks, whose preparation requires discrete design and constructive alignment of different chemistries. To enable future automation of the synthesis of small molecules, we have devised a unified strategy that serves the divergent synthesis of unrelated scaffolds such as carbonyls, olefins, organometallics, halides, and boronic esters. It is based on iterations of a nonelectrophilic Pummerer-type C-C coupling enabled by turbo -organomagnesium amides that we have recently reported. The pluripotency of sulfur allows the central building blocks to be obtained by regulating C-C bond formation through control of its redox state.

Place, publisher, year, edition, pages
2018. Vol. 29, no 10, p. 1329-1333
Keywords [en]
sulfur, Pummerer coupling, iterative synthesis, Grignard reagents
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-157695DOI: 10.1055/s-0036-1591864ISI: 000433554100012OAI: oai:DiVA.org:su-157695DiVA, id: diva2:1236158
Available from: 2018-07-31 Created: 2018-07-31 Last updated: 2018-07-31Bibliographically approved

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