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Palladium Nanoparticles Immobilized on an Aminopropyl-functionalized Silica-Magnetite Composite as a Recyclable Catalyst for Suzuki-Miyaura Reactions
Stockholm University, Faculty of Science, Department of Organic Chemistry. University of Zanjan, Iran.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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Number of Authors: 82018 (English)In: Chemistryselect, ISSN 2365-6549, Vol. 3, no 27, p. 7970-7975Article in journal (Refereed) Published
Abstract [en]

Herein, we describe the straightforward synthesis and thorough characterization of a magnetically-separable heterogeneous catalyst comprised of 1-3nm-sized Pd nanoparticles immobilized on a mesoporous silica-magnetite composite (Pd-0-AmP-SMC). Catalytic evaluations were conducted using Suzuki-Miyaura cross-couplings as the model reactions, for which this Pd nanocatalyst exhibited high performance in an environmentally-friendly solvent mixture. Additionally, this Pd nanocatalyst could be re-used up to five cycles without any observable loss of activity, and separation of the catalyst could be conveniently done by a magnet.

Place, publisher, year, edition, pages
2018. Vol. 3, no 27, p. 7970-7975
Keywords [en]
green solvent, heterogeneous catalysis, magnetically-separable, palladium nanoparticles, Suzuki-Miyaura reaction, magnetically-separable
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-159052DOI: 10.1002/slct.201801415ISI: 000439756200042OAI: oai:DiVA.org:su-159052DiVA, id: diva2:1244117
Available from: 2018-08-31 Created: 2018-08-31 Last updated: 2019-12-09Bibliographically approved

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Lati, Monireh PourghasemiNaeem, Muhammad IqbalÅkermark, BjörnVerho, Oscar
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