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Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0002-4575-7870
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Number of Authors: 92018 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 140, no 44, p. 14533-14537Article in journal (Refereed) Published
Abstract [en]

Conductive metal-organic frameworks (c-MOFs) have shown outstanding performance in energy storage and electrocatalysis. Varying the bridging metal species and the coordinating atom are versatile approaches to tune their intrinsic electronic properties in c-MOFs. Herein we report the first synthesis of the oxygen analog of M-3(C6X6)(2) (X = NH, S) family using Cu(II) and hexahydroxybenzene (HHB), namely Cu-HHB [Cu-3(C6O6)(2)], through a kinetically controlled approach with a competing coordination reagent. We also successfully demonstrate an economical synthetic approach using tetrahydroxyquinone as the starting material. Cu-HHB was found to have a partially eclipsed packing between adjacent 2D layers and a bandgap of approximately 1 eV. The addition of Cu-HHB to the family of synthetically realized M-3(C6X6)(2) c-MOFs will enable greater understanding of the influence of the organic linkers and metals, and further broadens the range of applications for these materials.

Place, publisher, year, edition, pages
2018. Vol. 140, no 44, p. 14533-14537
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Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-162745DOI: 10.1021/jacs.8b06666ISI: 000449887800002PubMedID: 30176142OAI: oai:DiVA.org:su-162745DiVA, id: diva2:1275074
Available from: 2019-01-04 Created: 2019-01-04 Last updated: 2019-12-17Bibliographically approved

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Park, JihyeHuang, ZhehaoZou, XiaodongBao, Zhenan
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