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Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-4249-7807
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-9199-6736
Number of Authors: 42019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 60, p. 8844-8847Article in journal (Refereed) Published
Abstract [en]

The oxidative rearrangement of 1,3-diketones is an underexplored alternative to enolate chemistry in the synthesis of all-carbon quaternary carboxylates. The mechanistic investigation of this reaction has resulted in a mild base mediated protocol, whose regioselectivity has been studied in challenging acyclic substrates.

Place, publisher, year, edition, pages
2019. Vol. 55, no 60, p. 8844-8847
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Chemical Sciences
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URN: urn:nbn:se:su:diva-171956DOI: 10.1039/c9cc03331aISI: 000476956800023PubMedID: 31169839OAI: oai:DiVA.org:su-171956DiVA, id: diva2:1348572
Available from: 2019-09-04 Created: 2019-09-04 Last updated: 2019-09-04Bibliographically approved

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