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Fast and Robust Synthesis of Metalated PCN-222 and Their Catalytic Performance in Cycloaddition Reactions with CO2
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0003-0024-1392
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-1729-598X
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 32019 (English)In: Organometallics, ISSN 0276-7333, E-ISSN 1520-6041, Vol. 38, no 18, p. 3429-3435Article in journal (Refereed) Published
Abstract [en]

A simple and quick setup for the synthesis of PCN-222 and of a variety of metalated PCN-222(Co, Ni, Cu, and Zn), using of a microwave reactor, is reported for CO2 fixation. Metalation of prophyrins by microwave heating has been evaluated through UV-vis titration. PCN-222(M) were obtained in a three-step, one-pot reaction in a remarkable 72% yield in only 30 min. The materials have been characterized using a variety of techniques. A study of CO2 fixation through cycloaddition with epoxides and azidirines using metalated PCNs as catalysts is described. Cyclic carbonates and oxazolidinones were formed using CO2 at atmospheric pressure under mild conditions. Higher activity was observed when PCN-222(Co) was used compared to that with PCN-222(Ni, Cu, Zn).

Place, publisher, year, edition, pages
2019. Vol. 38, no 18, p. 3429-3435
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Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-175708DOI: 10.1021/acs.organomet.9b00273ISI: 000487769900007OAI: oai:DiVA.org:su-175708DiVA, id: diva2:1369944
Available from: 2019-11-13 Created: 2019-11-13 Last updated: 2019-12-04Bibliographically approved

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Carrasco, SergioSanz-Marco, AmparoMartin-Matute, Belén
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