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Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose Nanocrystals
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). Helwan University, Egypt.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0001-8909-3554
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0003-1016-5135
Number of Authors: 42019 (English)In: ACS Macro Letters, E-ISSN 2161-1653, Vol. 8, no 10, p. 1372-1377Article in journal (Refereed) Published
Abstract [en]

Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 degrees C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.

Place, publisher, year, edition, pages
2019. Vol. 8, no 10, p. 1372-1377
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-175845DOI: 10.1021/acsmacrolett.9b00542ISI: 000491220800028OAI: oai:DiVA.org:su-175845DiVA, id: diva2:1369960
Available from: 2019-11-13 Created: 2019-11-13 Last updated: 2020-01-30Bibliographically approved

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Yahia, MohamedMathew, Aji P.Yuan, Jiayin
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