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Hydrogenated Gold Clusters from Helium Nanodroplets: Cluster Ionization and Affinities for Protons and Hydrogen Molecules
Stockholm University, Faculty of Science, Department of Physics. Universit├Ąt Innsbruck, Austria.ORCID iD: 0000-0003-1028-7976
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Number of Authors: 62019 (English)In: Journal of the American Society for Mass Spectrometry, ISSN 1044-0305, E-ISSN 1879-1123, Vol. 30, no 10, p. 1906-1913Article in journal (Refereed) Published
Abstract [en]

We report the mass spectrometric detection of hydrogenated gold clusters ionized by electron transfer and proton transfer. The cations appear after the pickup of hydrogen molecules and gold atoms by helium nanodroplets (HNDs) near zero K and subsequent exposure to electron impact. We focus on the size distributions of the gold cluster cations and their hydrogen content, the electron energy dependence of the ion yield, patterns of hydrogenated gold cluster cation stability, and the presence of magic clusters. Ab initio molecular orbital calculations were performed to provide insight into ionization energies and proton affinities of gold clusters as well as into molecular hydrogen affinities of the ionized and protonated gold cluster cations.

Place, publisher, year, edition, pages
2019. Vol. 30, no 10, p. 1906-1913
Keywords [en]
Hydrogenated gold cluster ions, Helium nanodroplets, Proton affinities, H-2 affinities
National Category
Chemical Sciences Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-175841DOI: 10.1007/s13361-019-02235-1ISI: 000491555700009PubMedID: 31168747OAI: oai:DiVA.org:su-175841DiVA, id: diva2:1370930
Available from: 2019-11-18 Created: 2019-11-18 Last updated: 2019-11-18Bibliographically approved

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Lundberg, LinneaMartini, PaulGatchell, MichaelScheier, Paul
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