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Mixed cationic clusters of nitrogen and hydrogen
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Number of Authors: 62020 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 152, no 1, article id 014303Article in journal (Refereed) Published
Abstract [en]

The addition of small impurities, such as a single proton charge carrier, in noble gas clusters has recently been shown to have considerable effects on their geometries and stabilities. Here, we report on a mass spectrometric study of cationic clusters of N-2 molecules and the effects that adding hydrogen, in the form of D-2, has on the systems. Protonated nitrogen clusters formed by the breakup of D-2 are shown to have similar behaviors as protonated rare gas clusters. For larger systems consisting of different mixtures of intact N-2 and D-2, different molecular species are found to be interchangeable sometimes with regard to magic numbers. This is especially true for the (N2)n(D-2)(m)D+ systems with n + m = 17, which is particularly abundant for all measured combinations of n and m.

Place, publisher, year, edition, pages
2020. Vol. 152, no 1, article id 014303
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Chemical Sciences Physical Sciences
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URN: urn:nbn:se:su:diva-178620DOI: 10.1063/1.5140850ISI: 000505578700009PubMedID: 31914740Scopus ID: 2-s2.0-85077541865OAI: oai:DiVA.org:su-178620DiVA, id: diva2:1414014
Available from: 2020-03-11 Created: 2020-03-11 Last updated: 2022-11-08Bibliographically approved

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Scheier, P.Gatchell, Michael

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