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Enhanced Light-Absorption of Black Carbon in Rainwater Compared With Aerosols Over the Northern Indian Ocean
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry. SMaldives Climate Observatory at Hanimaadhoo, Maldives; Indian Institute of Sciences (IISc), India.
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry.
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry.
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry. CSIR‐National Institute of Oceanography, India.
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Number of Authors: 72020 (English)In: Journal of Geophysical Research - Atmospheres, ISSN 2169-897X, E-ISSN 2169-8996, Vol. 125, no 2, article id e2019JD031246Article in journal (Refereed) Published
Abstract [en]

Black carbon (BC) aerosols affect climate, especially in high aerosol loading regions such as South Asia. A key uncertainty for the climate effects of BC is the evolution of light-absorbing properties in the atmosphere. Here, we present a year-round comparison of the mass absorption cross section (MAC; 678 nm) of BC in air (PM10) and rain, for samples collected at the Maldives Climate Observatory at Hanimaadhoo. We develop a filter-loading correction scheme for estimating BC absorption on filters used in high-volume samplers. The year-round average MAC(678) of BC in the rain is almost twice (13.3 +/- 4.2 m(2)/g) compared to the PM10 aerosol (7.2 +/- 2.6 m(2)/g). A possible explanation is the elevated ratio of organic carbon (OC) to BC observed in rain particulate matter (9.4 +/- 6.3) compared to in the aerosols (OC/BC 2.6 +/- 1.4 and water-insoluble organic carbon/BC 1.2 +/- 0.8), indicating a coating-enhancement effect. In addition to BC, we also investigated the MAC(365) of water-soluble brown carbon in PM10 (0.4 +/- 0.4 m(2)/g, at 365 nm). In contrast to BC, MAC(365)brown carbon relates to air mass history, showing higher values for samples from air originating over the South Asian landmass. Furthermore, calculated washout ratios are much lower for BC compared to OC and inorganic ions such as sulfate, implying a longer atmospheric lifetime for BC. The wet deposition flux for BC during the high loading winter was 3 times higher than during the wet summer, despite much less precipitation in the winter.

Place, publisher, year, edition, pages
2020. Vol. 125, no 2, article id e2019JD031246
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Earth and Related Environmental Sciences
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URN: urn:nbn:se:su:diva-181115DOI: 10.1029/2019JD031246ISI: 000521080000004OAI: oai:DiVA.org:su-181115DiVA, id: diva2:1426678
Available from: 2020-04-27 Created: 2020-04-27 Last updated: 2025-02-07Bibliographically approved

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Budhavant, KrishnakantAndersson, AugustHolmstrand, HenryBikkina, SrinivasGustafsson, Örjan

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