Non-Hermitian systems exhibit striking exceptions from the paradigmatic bulk-boundary correspondence, including the failure of bulk Bloch band invariants in predicting boundary states and the (dis) appearance of boundary states at parameter values far from those corresponding to gap closings in periodic systems without boundaries. Here, we provide a comprehensive framework to unravel this disparity based on the notion of biorthogonal quantum mechanics: While the properties of the left and right eigenstates corresponding to boundary modes are individually decoupled from the bulk physics in non-Hermitian systems, their combined biorthogonal density penetrates the bulk precisely when phase transitions occur. This leads to generalized bulk-boundary correspondence and a quantized biorthogonal polarization that is formulated directly in systems with open boundaries. We illustrate our general insights by deriving the phase diagram for several microscopic open boundary models, including exactly solvable non-Hermitian extensions of the Su-Schrieffer-Heeger model and Chern insulators.

Non-Hermitian Hamiltonians, which describe a wide range of dissipative systems, and higher-order topological phases, which exhibit novel boundary states on corners and hinges, comprise two areas of intense current research. Here we investigate systems where these frontiers merge and formulate a generalized biorthogonal bulk-boundary correspondence, which dictates the appearance of boundary modes at parameter values that are, in general, radically different from those that mark phase transitions in periodic systems. By analyzing the interplay between corner/hinge, edge/surface and bulk degrees of freedom we establish that the non-Hermitian extensions of higher-order topological phases exhibit an even richer phenomenology than their Hermitian counterparts and that this can be understood in a unifying way within our biorthogonal framework. Saliently this works in the presence of the non-Hermitian skin effect, and also naturally encompasses genuinely non-Hermitian phenomena in the absence thereof.