Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry. Karlsruhe Institute of Technology, Germany.
Show others and affiliations
Number of Authors: 132020 (English)In: Atmospheric Chemistry And Physics, ISSN 1680-7316, E-ISSN 1680-7324, Vol. 20, no 9, p. 5629-5644Article in journal (Refereed) Published
Abstract [en]

Secondary organic aerosol (SOA) is an important constituent of the atmosphere where SOA particles are formed chiefly by the condensation or reactive uptake of oxidation products of volatile organic compounds (VOCs). The mass yield in SOA particle formation, as well as the chemical composition and volatility of the particles, is determined by the identity of the VOC precursor(s) and the oxidation conditions they experience. In this study, we used an oxidation flow reactor to generate biogenic SOA from the oxidation of Scots pine emissions. Mass yields, chemical composition and volatility of the SOA particles were characterized and compared with SOA particles formed from oxidation of alpha-pinene and from a mixture of acyclic-monocyclic sesquiterpenes (farnesenes and bisabolenes), which are significant components of the Scots pine emissions. SOA mass yields for Scots pine emissions dominated by farnesenes were lower than for a-pinene but higher than for the artificial mixture of farne-senes and bisabolenes. The reduction in the SOA yield in the farnesene- and bisabolene-dominated mixtures is due to exocyclic C =C bond scission in these acyclic-monocyclic sesquiterpenes during ozonolysis leading to smaller and generally more volatile products. SOA particles from the oxi- dation of Scots pine emissions had similar or lower volatility than SOA particles formed from either a single precursor or a simple mixture of VOCs. Applying physical stress to the Scots pine plants increased their monoterpene, especially monocyclic beta-phellandrene, emissions, which further decreased SOA particle volatility and increased SOA mass yield. Our results highlight the need to account for the chemical complexity and structure of real-world biogenic VOC emissions and stress-induced changes to plant emissions when modelling SOA production and properties in the atmosphere. These results emphasize that a simple increase or decrease in relative monoterpene and sesquiterpene emissions should not be used as an indicator of SOA particle volatility.

Place, publisher, year, edition, pages
2020. Vol. 20, no 9, p. 5629-5644
National Category
Earth and Related Environmental Sciences
Identifiers
URN: urn:nbn:se:su:diva-182992DOI: 10.5194/acp-20-5629-2020ISI: 000535189200004OAI: oai:DiVA.org:su-182992DiVA, id: diva2:1452381
Available from: 2020-07-06 Created: 2020-07-06 Last updated: 2025-02-07Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full text

Authority records

Mohr, ClaudiaNizkorodov, Sergey A.

Search in DiVA

By author/editor
Mohr, ClaudiaNizkorodov, Sergey A.
By organisation
Department of Environmental Science and Analytical Chemistry
In the same journal
Atmospheric Chemistry And Physics
Earth and Related Environmental Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 107 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf