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Development of a high pressure stirring cell up to 2 GPa: a new window for chemical reactions and material synthesis
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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Number of Authors: 52020 (English)In: High Pressure Research, ISSN 0895-7959, E-ISSN 1477-2299, Vol. 40, no 3, p. 358-368Article in journal (Refereed) Published
Abstract [en]

A new method for stirring under high pressure conditions has been developed and tested. The key component is a Teflon cell assembly equipped with magnetic stirring function, which is capable to operate across a wide pressure range, up to at least 2 GPa, in a large volume press. The setup enables adjustable stirrer rotation rate and detection of stirring in a sample,e.g.to observe liquid-solid phase transitions at high pressure. The viscosity limit of stirring is ca. 500 times that of water at room temperature (i.e.similar to 500 mPas). Moreover, we show that zinc oxide nanoparticles hydrothermally synthesized at 0.5 GPa and 100 degrees C under stirring conditions show an order of magnitude smaller size (100 nm) compared to those synthesized under non-stirring conditions (1 mu m). The wide pressure range for stirring of viscous media opens interesting possibilities to produce novel materials via hydrothermal synthesis and chemical reactions.

Place, publisher, year, edition, pages
2020. Vol. 40, no 3, p. 358-368
Keywords [en]
Magnetic stirring, hydrothermal synthesis, high pressure, metal oxide
National Category
Chemical Sciences Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-183667DOI: 10.1080/08957959.2020.1775200ISI: 000542735100001OAI: oai:DiVA.org:su-183667DiVA, id: diva2:1455374
Available from: 2020-07-23 Created: 2020-07-23 Last updated: 2022-02-26Bibliographically approved

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Gordeeva, AlisaHäussermann, Ulrich

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