We present observations of the solar chromosphere obtained simultaneously with the Atacama Large Millimeter/submillimeter Array (ALMA) and the Interface Region Imaging Spectrograph. The observatories targeted a chromospheric plage region of which the spatial distribution (split between strongly and weakly magnetized regions) allowed the study of linear-like structures in isolation, free of contamination from background emission. Using these observations in conjunction with a radiative magnetohydrodynamic 2.5D model covering the upper convection zone all the way to the corona that considers nonequilibrium ionization effects, we report the detection of an on-disk chromospheric spicule with ALMA and confirm its multithermal nature.