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A germanate built from 68126 cavity co-templated by a (H2O)16 water cluster and 2-methylpiperazine
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
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2008 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 47, no 41, 7868-7871 p.Article in journal (Refereed) Published
Abstract [en]

Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X=O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green).

Place, publisher, year, edition, pages
2008. Vol. 47, no 41, 7868-7871 p.
Keyword [en]
* cluster compounds; * germanates; * hydrogen bonds; * solvothermal synthesis; * tubular structures
National Category
Chemical Sciences
URN: urn:nbn:se:su:diva-15431DOI: doi:10.1002/anie.200801375ISI: 000260062500016OAI: diva2:181951
Available from: 2008-12-02 Created: 2008-12-02 Last updated: 2010-09-13Bibliographically approved

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Zou, XiaodongSun, Junliang
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Department of Physical, Inorganic and Structural Chemistry
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