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Synthesis of Novel Heteroaryl Iodonium Salts and Enantioselective a-Arylation of Cyclohexanones
Stockholm University, Faculty of Science, Department of Organic Chemistry. (Olofsson)
Bristol University, UK.
2006 (English)In: 2nd Int. Conference on Hypervalent Iodine, 2006Conference paper, Published paper (Other academic)
Abstract [en]

We have developed a direct arylation reaction of cyclohexanones employing diaryl iodonium(Ill) salts as electrophiles. The

reaction was made enantiosilective by the use of a chiral base, resultinginZ,4-disubstituted cyclohexanones in high yields and with high enantiomeric excesses and diastereoselectivities. Novel heteroaryl iodonium salts were subsequently synthesized and employed in the coupling to variously substituted cyclohexanones.

Place, publisher, year, edition, pages
2006.
National Category
Organic Chemistry
Research subject
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-20422OAI: oai:DiVA.org:su-20422DiVA: diva2:186948
Conference
2nd Int. Conference on Hypervalent Iodine
Funder
Swedish Research Council
Available from: 2007-03-28 Created: 2007-03-28 Last updated: 2014-10-29Bibliographically approved

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2nd ICHIC(3977 kB)28 downloads
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Type fulltextMimetype application/pdf

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CiteExportLink to record
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