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Crystal Structure and magnetic properties of Cu3(TeO3)2Br2 – a layered compound with a new Cu(II) coordination polyhedron
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
2006 In: Journal of Solid State Chemistry, ISSN 0022-4596, Vol. 178, no 6, 2024-2029 p.Article in journal (Refereed) Published
Place, publisher, year, edition, pages
2006. Vol. 178, no 6, 2024-2029 p.
Identifiers
URN: urn:nbn:se:su:diva-23084OAI: oai:DiVA.org:su-23084DiVA: diva2:190054
Note
Part of urn:nbn:se:su:diva-1414Available from: 2007-01-02 Created: 2007-01-02Bibliographically approved
In thesis
1. Terminating species and Lewis acid-base preference in oxohalides – a new route to low-dimensional compounds
Open this publication in new window or tab >>Terminating species and Lewis acid-base preference in oxohalides – a new route to low-dimensional compounds
2007 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis is based upon synthesis and structure determination of new transition metal oxo-halide compounds, which includes p-element cations that have a stereochemically active lone pair. A synthesis concept has been developed, which uses several different structural features to increase the possibility to yield a low-dimensional arrangement of transition metal cations. A total of 17 new compounds has been synthesised and their structures have been determined via single-crystal X-ray diffraction. The halides and the stereochemically active lone-pairs will typically act as terminating species segregating into regions of non-bonding volumes, which may take the form of 2D layers, 1D channels or Euclidean spheres. The transition metals that have been used for this work are copper, cobalt and iron. The Hard-Soft-Acid-Base principle has been utilized to match strong Lewis acids to strong Lewis bases and weak acids to weak bases. All compounds show tendencies towards low-dimensionality; they all have sheets of transition metal cations arranged into layers, where the layers most often are connected via weak dispersion forces.

Place, publisher, year, edition, pages
Stockholm: Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi, 2007. 174 p.
Keyword
Low dimensionality, crystal structures, tellurites, selenites, oxohalides
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:su:diva-1414 (URN)91-7155-365-7 (ISBN)
Public defence
2007-02-02, Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 12 A, Stockholm, 10:00
Opponent
Supervisors
Available from: 2007-01-02 Created: 2007-01-02Bibliographically approved

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