A New, Dinuclear High Spin Manganese(III) Complex with Bridging Phenoxy and Methoxy Groups. Structure and Magnetic Properties
2006 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 9, no 12, 1195-1198 p.Article in journal (Refereed) Published
A new μ-phenoxy-μ-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn–Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm−1
Place, publisher, year, edition, pages
2006. Vol. 9, no 12, 1195-1198 p.
Manganese complex, X-ray structure, Magnetic properties
IdentifiersURN: urn:nbn:se:su:diva-23607DOI: 10.1016/j.inoche.2006.07.025OAI: oai:DiVA.org:su-23607DiVA: diva2:193359