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A germanate built from from 68126 cavity co-templated by a (H2O)16 water cluster and 2-methylpiperazine
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
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2008 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773Article in journal (Refereed) Submitted
Place, publisher, year, edition, pages
National Category
Organic Chemistry
URN: urn:nbn:se:su:diva-24859OAI: diva2:198431

Part of urn:nbn:se:su:diva-7501

Available from: 2008-04-24 Created: 2008-04-24 Last updated: 2015-10-16Bibliographically approved
In thesis
1. Open-Framework Germanates: Crystallography, structures and cluster building units
Open this publication in new window or tab >>Open-Framework Germanates: Crystallography, structures and cluster building units
2008 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis is focussing on the crystallographic challenges and what knowledge we can gain from studying the different open-framework germanates. Five new open-framework germanates have been synthesized and the structures have been determined by single crystal X-ray diffraction. A thorough description is made of the different problems raised with the different compounds, whether it is choice of crystal system in SU-61, twinning and possible ordering in SU-46, superstructure and variation in elemental content in SU-57, template disorder in JLG-5 or framework disorder in SU-44.

Open-framework germanates are often built from one type of cluster, such as the Ge7 [Ge7X19], Ge8 [Ge8X20], Ge9 [Ge9Xn, n =25-26] and Ge10 [Ge10X28], (X =O, OH, F) clusters. The structures built by clusters containing different kinds of polyhedra are discussed, with a focus on the 4-coordinated Ge7 clusters, the larger cluster aggregate found in SU-8 and SU-44 and the structures built by the Ge10 clusters.

Place, publisher, year, edition, pages
Stockholm: Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi, 2008. 90 p.
germanate, crystallography, building unit, zeotype, scale chemistry
National Category
Chemical Sciences
Research subject
Structural Chemistry
urn:nbn:se:su:diva-7501 (URN)978-91-7155-570-0 (ISBN)
Public defence
2008-05-16, Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 12 A, Stockholm, 10:00
Available from: 2008-04-24 Created: 2008-04-24Bibliographically approved

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