Regiospecific One-Pot Synthesis of Diaryliodonium Tetrafluoroborates from Arylboronic Acids and Aryl Iodides
Stockholm University, Faculty of Science, Department of Organic Chemistry2008 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 73, no 12, 4602-4607 p.Article in journal (Refereed) Published
Diaryliodonium salts have recently received considerable attention as mild arylation reagents in organic synthesis. This paper describes a regiospecific, sequential one-pot synthesis of symmetrical and unsymmetrical diaryliodonium tetrafluoroborates, which are the most popular salts in metal-catalyzed arylations. The protocol is fast and high-yielding and has a large substrate scope. Furthermore, the corresponding diaryliodonium triflates can conveniently be obtained via an in situ anion exchange.
Place, publisher, year, edition, pages
2008. Vol. 73, no 12, 4602-4607 p.
diaryliodonium salts, MCPBA
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-25301DOI: 10.1021/jo8004974ISI: 000256757100030OAI: oai:DiVA.org:su-25301DiVA: diva2:199371
FunderSwedish Research Council, 621-2006-4027