Development of Multi-Component Reactions using Catalytically Generated Allyl Metal Reagents
Stockholm University, Faculty of Science, Department of Organic Chemistry2008 (English)Licentiate thesis, comprehensive summary (Other academic)
This licentiate thesis is based on the development of catalytic reactions for the synthesis and application of organometallic reagents. By use of palladium pincer-complex catalysts, we have developed an efficient procedure for the synthesis of allylboronates starting from allylic alcohols. These reactions were further extended by including various one-pot multi-component reactions, using the in situ generated allylboronates. Furthermore, novel unsymmetrical palladium pincer-complexes were synthesized and studied in auto-tandem catalysis.
Place, publisher, year, edition, pages
Stockholms universitet , 2008. , 54 p.
IdentifiersURN: urn:nbn:se:su:diva-8077OAI: oai:DiVA.org:su-8077DiVA: diva2:199538