Pincer Complex-Catalyzed Coupling Reactions via Palladium (IV) Intermediates
2009 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 11, no 13, 2852-2854 p.Article in journal (Refereed) Published
Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably occurs through Pd(IV) intermediates. Due to the strong metal−ligand interactions, the oxidation of phosphine and amine ligands of the pincer complexes can be avoided in the presented reactions.
Place, publisher, year, edition, pages
2009. Vol. 11, no 13, 2852-2854 p.
IdentifiersURN: urn:nbn:se:su:diva-25756DOI: 10.1021/ol9010739OAI: oai:DiVA.org:su-25756DiVA: diva2:200432
Part of urn:nbn:se:su:diva-85242009-02-262009-02-172013-05-02Bibliographically approved