Pincer complex-catalyzed redox coupling of alkenes with iodonium salts via presumed palladium(IV) intermediates
2009 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 11, no 13, 2852-2854 p.Article in journal (Refereed) Published
Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably occurs through Pd(IV) intermediates. Due to the strong metal−ligand interactions, the oxidation of phosphine and amine ligands of the pincer complexes can be avoided in the presented reactions.
Place, publisher, year, edition, pages
American Chemical Society , 2009. Vol. 11, no 13, 2852-2854 p.
IdentifiersURN: urn:nbn:se:su:diva-29393DOI: 10.1021/ol9010739ISI: 000267400100035OAI: oai:DiVA.org:su-29393DiVA: diva2:232834