Performance of SCS palladium pincer complexes in borylation of allylic alcohols. Control of the regioselectivity in the one-pot borylation-allylation process
2009 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 74, no 15, 5695-5698 p.Article in journal (Refereed) Published
One-pot borylation−allylation reactions of aldehydes and allylic alcohols were performed under various reaction conditions. The borylation of allylic alcohols was performed using a very efficient SCS palladium pincer-complex catalyst. The regioselectivity of the allylation depends on the applied solvent. The reaction in CHCl3 gave the linear allylic product; however, when MeOH was added to the reaction mixture, the branched allylic product was formed.
Place, publisher, year, edition, pages
American Chemical Society , 2009. Vol. 74, no 15, 5695-5698 p.
IdentifiersURN: urn:nbn:se:su:diva-31751DOI: 10.1021/jo9008673ISI: 000268480300090OAI: oai:DiVA.org:su-31751DiVA: diva2:278464