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Heterogeneous Rh-Catalyzed Reactions of Allylic Alcohols
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Structural Chemistry.
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Structural Chemistry.
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2009 (English)Conference paper, Published paper (Other academic)
Abstract [en]

The development of metal-catalyzed reactions that are atom-economical, environmentally benign, and highly selective and that take place under mild reaction conditions is of extreme importance. The isomerization of allylic alcohols to the corresponding carbonyl compounds can be catalyzed by transition metal complexes. We have shown before that this transformation involves the formation of metal enolates. When this isomerization is performed under homogeneous conditions in the presence of an electrophile, a new C-C bond is formed in a regioselective manner.

1 Here, we present our studies towards the use of immobilized transition metal complexes as heterogeneous catalysts in tandem transformations of allylic alcohols. Different strategies and supports for the immobilization have been compared in this study.

Place, publisher, year, edition, pages
2009. P114- p.
Identifiers
URN: urn:nbn:se:su:diva-31960OAI: oai:DiVA.org:su-31960DiVA: diva2:279042
Conference
The 14th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis, Stockholm, September 13-18, 2009.
Note
Endast Abstract publiceratAvailable from: 2009-12-01 Created: 2009-12-01 Last updated: 2011-10-12Bibliographically approved

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