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Chemical Bonding on Metal Surfaces : Synergy between Theory and Experiment
Stockholm University, Faculty of Science, Department of Physics. (Kvantkemi)
Stockholm University, Faculty of Science, Department of Physics. (Kvantkemi)
2010 (English)In: Model Systems in Catalysis :  From Single Crystals and Size-Selected Clusters to Supported Enzyme Mimics / [ed] Robert Rioux, Springer Verlag , 2010Chapter in book (Other academic)
Abstract [en]

X-ray spectroscopy provides a number of experimental techniques that give an atom-specific projection of the electronic structure. When applied to surface adsorbates in combination with theoretical density functional spectrum simulations, it becomes an extremely powerful tool to analyze in detail the surface chemical bond. This is of great relevance to heterogeneous catalysis as discussed in depth for a number of example systems taken from the five categories of bonding types: (i) atomic radical, (ii) diatomics with unsaturated π-systems (Blyholder model), (iii) unsaturated hydrocarbons (Dewar–Chatt–Duncanson model), (iv) lone-pair interactions, and (v) saturated hydrocarbons (physisorption)

Place, publisher, year, edition, pages
Springer Verlag , 2010.
National Category
Subatomic Physics
Research subject
Chemical Physics
URN: urn:nbn:se:su:diva-32146DOI: 10.1007/978-0-387-98049-2_12ISBN: 978-0-387-98041-6OAI: diva2:279642
Available from: 2009-12-04 Created: 2009-12-04 Last updated: 2011-09-13Bibliographically approved

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Nilsson, AndersPettersson, Lars G.M.
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Department of Physics
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