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 Two for the price of one  resolvable polymorphism in a single crystalof a- and b-Sb3O4I
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
2009 (English)In: Solid State Sciences, ISSN 1293-2558, E-ISSN 1873-3085, Vol. 11, no 1, 24-28 p.Article in journal (Refereed) Published
Abstract [en]

The title compound forms as biphasic single crystals containing the  and  polymorphs. The structure of both polymorphs was solved and refined from single crystal X-ray data in a simultaneous refinement. The structures consist of rods of composition Sb3O4 separated by isolated iodine ions. The two phases differ only in the next nearest neighbour arrangement. The orthorhombic -phase crystallizes in space group Pbn21, and the monoclinic -phase in space group P21/n

Place, publisher, year, edition, pages
2009. Vol. 11, no 1, 24-28 p.
Keyword [en]
stereochemically active lone pair, multiphase crystal, oxyhalide
Identifiers
URN: urn:nbn:se:su:diva-35454DOI: 10.1016/j.solidstatesciences.2008.04.028ISI: 000262753300003OAI: oai:DiVA.org:su-35454DiVA: diva2:287586
Available from: 2010-01-19 Created: 2010-01-18 Last updated: 2017-12-12Bibliographically approved

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