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Separation of the oxide and halide part inthe oxohalide Fe3Te3O10Cl due to high Lewis acidity of the cations
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
2009 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 48, 6599-6603 p.Article in journal (Refereed) Published
Abstract [en]

crystallizes in the monoclinic space group P21/c. The crystal structure comprises channels where the Cl ions and also the stereochemically active lone-pair electrons on Te4+ are located. The Cl-atoms rather act as counter ions than being part of the covalent/ionic network. The magnetic susceptibility indicates antiferromagnetic ordering below TN~100 K with a marked splitting of the field cooled (fc) and the zero-field cooled (zfc) susceptibility at low magnetic fields; the splitting disappears at higher magnetic fields. Heat capacity measurements confirm the long range ordering at below this temperature. Only moderate shifts are observed with Raman spectroscopy at the magnetic transition

Place, publisher, year, edition, pages
2009. Vol. 48, 6599-6603 p.
Keyword [en]
Crystal-structcture determination, oxohalide, Te, Lewisacids/bases, Magnetic properties
National Category
Inorganic Chemistry
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-35470DOI: 10.1021/ic9005778ISI: 000268137900040OAI: oai:DiVA.org:su-35470DiVA: diva2:287589
Note
övrigt antal författare 2st.Available from: 2010-01-19 Created: 2010-01-18 Last updated: 2017-12-12Bibliographically approved

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