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(I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry.
2009 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 48, no 23, 10883-10885 p.Article in journal (Refereed) Published
Abstract [en]

Biphenyl-2,2′-dithiolate (bpdt) bridged Fe2(bpdt)(CO)6 (1) undergoes two sequential electrochemically quasi-reversible reductions. The one-electron reduction product 1 is unusually stable against irreversible structural changes and could be characterized by IR and EPR spectroscopy supported by computational methods. Reduction to the (I,0) state does not trigger bridging coordination of CO but partial deligation of the dithiolate in 1 that ultimately forms a diamagnetic dimerization product.

Place, publisher, year, edition, pages
2009. Vol. 48, no 23, 10883-10885 p.
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Inorganic Chemistry
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-34871DOI: 10.1021/ic9016454ISI: 000272037500010OAI: oai:DiVA.org:su-34871DiVA: diva2:288524
Note
antal övriga författare 5st.Available from: 2010-01-21 Created: 2010-01-13 Last updated: 2017-12-12Bibliographically approved

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