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High Resolution Spectroscopy of Singly Charged Ions: Applications of Laser and Fourier Transform Techniques
Stockholm University, Faculty of Science, Department of Physics. (Atomic Physics)
2010 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis presents measurements of fundamental properties of singly charged ionic systems including spectral wavelengths, lifetimes of excited states and branching fractions with the main focus on time resolved laser spectroscopy of stored ions providing lifetime measurements of metastable states. The results of these measurements have been used to determine energy levels and transition probabilities of the studied systems. The included experimental data are compared with results from calculations which provides evaluations of different theoretical models. The presented results have been applied by others to the field of atomic astrophysics in order to deduce electron densities and elemental abundances in ejecta of the supermassive star eta Carinae and have also been followed by additional work of theoreticians interested in comparisons with laboratory data. The thesis is a result of several collaborations in which Stockholm University has been providing lifetime measurements of metastable states, Lund Observatory and the National Institute of Standards and Technology have been providing wavelength and branching fraction measurements, Lund Laser Centre has been providing lifetime measurements of short-lived states and calculations have been performed by theoretical physicists from Université de Mons-Hainaut, Université de Liège, Queen's University of Belfast and Laboratoire Aimé Cotton.

Place, publisher, year, edition, pages
Stockholm: Department of Physics, Stockholm University , 2010. , 99 p.
National Category
Atom and Molecular Physics and Optics
Research subject
Physics
Identifiers
URN: urn:nbn:se:su:diva-42627ISBN: 978-91-7447-134-2 (print)OAI: oai:DiVA.org:su-42627DiVA: diva2:350362
Public defence
2010-10-22, FB42, AlbaNova universitetscentrum, Roslagstullsbacken 21, Stockholm, 13:00 (English)
Opponent
Supervisors
Available from: 2010-09-30 Created: 2010-09-10 Last updated: 2010-10-01Bibliographically approved
List of papers
1. Laser-probing measurements and calculations of lifetimes of the 5d 2D3/2 and 5d 2D5/2 metastable levels in Ba II
Open this publication in new window or tab >>Laser-probing measurements and calculations of lifetimes of the 5d 2D3/2 and 5d 2D5/2 metastable levels in Ba II
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2007 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 75, no 5, 052506- p.Article in journal (Refereed) Published
Abstract [en]

The two metastable levels 5d 2D3∕2 and 5d 2D5∕2 in Ba II both show extremely long lifetimes of the order of several tens of seconds each. This has been found both by experiments and by theoretical predictions. The small transition probabilities associated with these two levels make them interesting and challenging for theoreticians as well as for experimentalists. Several calculations and measurements of these two lifetimes have been made previously but discrepancies between the results are present. This article presents values of τ=89.4±15.6 s for the 2D3∕2 level and τ=32.0±4.6 s for the 2D5∕2 level measured in a beam-laser experiment performed at the ion storage ring CRYRING. These values are supported by our new calculations resulting in τ=82.0 s for the 2D3∕2 level and τ=31.6 s for the 2D5∕2 level.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-25161 (URN)10.1103/PhysRevA.75.052506 (DOI)000246890400083 ()
Note
Part of urn:nbn:se:su:diva-7768Available from: 2008-05-27 Created: 2008-05-20 Last updated: 2017-12-13Bibliographically approved
2. Monitoring the weak collisional excitation of a stored ion beam reveals the radiative decay rate of extremely long-lived metastable levels
Open this publication in new window or tab >>Monitoring the weak collisional excitation of a stored ion beam reveals the radiative decay rate of extremely long-lived metastable levels
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2007 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 76, no 3, 030502- p.Article in journal (Refereed) Published
Abstract [en]

A fast ion beam stored in an ion storage ring will suffer from collisional interaction with the residual gas even in extreme ultrahigh vacuum. Normally these effects are negligible or easy to correct for. For measurements of extremely long radiative lifetimes of metastable levels we have found that correction for collisional effects is very important and usually limits the accuracy. We now suggest that by monitoring the process of collisional excitation of the metastable level of interest the lifetime value could be determined directly with improved accuracy. The method is applied to available data from our recent measurement of the 5d 2D5∕2 level in Ba+, yielding a value of 32.0±2.9 s, thus squeezing the error bar by 35%.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-25162 (URN)10.1103/PhysRevA.76.030502 (DOI)000249786000010 ()
Note
Part of urn:nbn:se:su:diva-7768Available from: 2008-05-27 Created: 2008-05-20 Last updated: 2017-12-13Bibliographically approved
3. Inclusion of Electric Octupole Contributions Explains the Fast Radiative Decays of Two Metastable States in Ar+
Open this publication in new window or tab >>Inclusion of Electric Octupole Contributions Explains the Fast Radiative Decays of Two Metastable States in Ar+
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2007 (English)In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 99, 213001- p.Article in journal (Refereed) Published
Abstract [en]

A laser probing investigation has yielded the lifetimes of the 3s23p4(1D)3d 2G7/2,9/2 metastable doublet states of Ar+. The results, obtained with the CRYRING ion storage ring of Stockholm, are 3.0±0.4 and 2.1±0.1  s, respectively. Comparisons with theoretical values calculated with two independent theoretical approaches, i.e., the pseudorelativistic Hartree-Fock method and the multiconfiguration Breit-Pauli approach, have allowed us to establish the unexpected and extraordinary strong contribution of an electric octupole (E3) transition to the ground state, in addition to the M1 decay channels to the 3d 2,4F states and the E2 contributions to the 4s 2P, 2D states.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-12437 (URN)10.1103/PhysRevLett.99.213001 (DOI)000251107500017 ()
Available from: 2008-01-15 Created: 2008-01-15 Last updated: 2017-12-13Bibliographically approved
4. The FERRUM project: Experimental and theoretical transition rates of forbidden [Sc II] lines and radiative lifetimes of metastable Sc II levels
Open this publication in new window or tab >>The FERRUM project: Experimental and theoretical transition rates of forbidden [Sc II] lines and radiative lifetimes of metastable Sc II levels
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2008 (English)In: Astronomy and Astrophysics, ISSN 0004-6361, E-ISSN 1432-0746, Vol. 480, no 2, 575-580 p.Article in journal (Refereed) Published
Abstract [en]

Context. In many plasmas, long-lived metastable atomic levels are depopulated by collisions (quenched) before they decay radiatively. In low-density regions, however, the low collision rate may allow depopulation by electric dipole (E1) forbidden radiative transitions, so-called forbidden lines (mainly M1 and E2 transitions). If the atomic transition data are known, these lines are indicators of physical plasma conditions and used for abundance determination.

Aims. Transition rates can be derived by combining relative intensities between the decay channels, so-called branching fractions (BFs), and the radiative lifetime of the common upper level. We use this approach for forbidden [Sc II] lines, along with new calculations.

Methods. Neither BFs for forbidden lines, nor lifetimes of metastable levels, are easily measured in a laboratory. Therefore, astrophysical BFs measured in Space Telescope Imaging Spectrograph (STIS) spectra of the strontium filament of Eta Carinae are combined with lifetime measurements using a laser probing technique on a stored ion-beam (CRYRING facility, MSL, Stockholm). These quantities are used to derive the absolute transition rates (A-values). New theoretical transition rates and lifetimes are calulated using the CIV3 code.

Results. We report experimental lifetimes of the Sc II levels 3d2 a3P0,1,2 with lifetimes 1.28, 1.42, and 1.24 s, respectively, and transition rates for lines from these levels down to 3d4s a3D in the region 8270-8390 Å. These are the most important forbidden [Sc II] transitions. New calculations for lines and metastable lifetimes are also presented, and are in good agreement with the experimental data.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-14409 (URN)10.1051/0004-6361:20079057 (DOI)000253806700034 ()
Available from: 2008-10-03 Created: 2008-10-03 Last updated: 2017-12-13Bibliographically approved
5. Lifetimes of metastable levels of singly ionized titanium : theory and experiment
Open this publication in new window or tab >>Lifetimes of metastable levels of singly ionized titanium : theory and experiment
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2008 (English)In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 41, no 12Article in journal (Refereed) Published
Abstract [en]

This paper presents new theoretical lifetimes of metastable levels in singly ionized titanium, Ti II. Along with the lifetimes, transition probabilities for several decay channels from these metastable levels are presented. The calculations are supported by experimental lifetime determinations of the 3d3 b 2D5/2 and 3d2(3P)4s b 2P3/2 levels along with revised values of the previously published lifetimes of the 3d2(3P)4s b 4P5/2 and 3d2(3P)4s b 2P1/2 levels originating partly from a reanalysis utilizing a recently developed method applied on the previously recorded data and partly from new measurements. The presented theoretical investigation of lifetimes of metastable levels in Ti II shows that the HFR calculations are in general compatible with measurements performed using the ion storage ring CRYRING of Stockholm University. The transition probabilities of forbidden lines derived from the new lifetime values will be useful for the diagnostics of low density laboratory or astrophysical plasmas, particularly those encountered in the strontium filament found in the ejecta of η Carinae.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-25164 (URN)10.1088/0953-4075/41/12/125703 (DOI)000257177700017 ()
Note
Part of urn:nbn:se:su:diva-7768Available from: 2008-05-27 Created: 2008-05-20 Last updated: 2017-12-13Bibliographically approved
6. Metastable levels in ScII: Lifetime measurements and calculations
Open this publication in new window or tab >>Metastable levels in ScII: Lifetime measurements and calculations
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2008 (Swedish)In: Physica scripta. T, ISSN 0281-1847, Vol. 78, no 1, 015301- p.Article in journal (Refereed) Published
Abstract [en]

The lifetime of the metastable level 3d2 1G4 in a singly charged scandium has been experimentally investigated at the ion storage ring CRYRING. A laser probing technique has been used for the studies. We also report calculated lifetimes and transition rates for 10 metastable levels in Sc II, including the 3d2 1G4 state, by calculations using configuration interaction wave functions. The lifetime of the 1G4 level is experimentally determined to be τexp=2.64±0.18 s and is in good agreement with the theoretical calculation τth=2.84 s.

National Category
Physical Sciences
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-14528 (URN)10.1088/0031-8949/78/01/015301 (DOI)000258143600018 ()
Available from: 2008-10-03 Created: 2008-10-03 Last updated: 2017-12-13Bibliographically approved
7. Wavelengths, energy levels and HFS in Ho II
Open this publication in new window or tab >>Wavelengths, energy levels and HFS in Ho II
2009 (English)In: Physica Scripta, ISSN 0031-8949, E-ISSN 1402-4896, Vol. 79, no 3, 035306- p.Article in journal (Refereed) Published
Abstract [en]

We recorded spectra of Ho II emitted by hollow-cathode lamps, using the ultraviolet Fourier transform spectrometer (FTS) at Lund Observatory and the 2-m FTS at the National Institute of Standards and Technology. The combined wavenumber coverage spans the interval from 8000 cm-1 to 49600 cm-1(12500 Å to 2016 Å). We measured 303 lines in these spectra and used them to determine energies and hyperfine structure constants of 100 levels. Ofthese, 41 energy levels have not been reported previously and hyperfine structure constants have not been reported previously for 83 levels. Comparisonsbetween the hyperfine structure constants and energy levels presented in this article and those previously determined from other studies are included anddiscrepancies are discussed. A theoretical study of the odd-parity levels leads to hyperfine structure parameters and to predictions for unknown excited levelsof the ground-state configuration.

National Category
Atom and Molecular Physics and Optics
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-27771 (URN)10.1088/0031-8949/79/03/035306 (DOI)000263891000013 ()
Available from: 2009-05-18 Created: 2009-05-18 Last updated: 2017-12-13Bibliographically approved
8. The FERRUM project: Transition probabilities for forbidden lines in [Fe II] and experimental metastable lifetimes
Open this publication in new window or tab >>The FERRUM project: Transition probabilities for forbidden lines in [Fe II] and experimental metastable lifetimes
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2009 (English)In: Astronomy and Astrophysics, ISSN 0004-6361, E-ISSN 1432-0746, Vol. 508, no 1, 525-529 p.Article in journal (Refereed) Published
Abstract [en]

Context. Accurate transition probabilities for forbidden lines are important diagnostic parameters for low-density astrophysical plasmas. In this paper we present experimental atomic data for forbidden [Fe II] transitions that are observed as strong features in astrophysical spectra. Aims. We measure lifetimes for the 3d(6)((3)G)4s a (4)G(11/2) and 3d(6)((3)D)4s b (4)D(1/2) metastable levels in Fe II and experimental transition probabilities for the forbidden transitions 3d(7) a (4)F(7/2,9/2)-3d(6)((3)G)4s a (4)G(11/2). Methods. The lifetimes were measured at the ion storage ring facility CRYRING using a laser probing technique. Astrophysical branching fractions were obtained from spectra of Eta Carinae, obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope. The lifetimes and branching fractions were combined to yield absolute transition probabilities. Results. The lifetimes of the a (4)G(11/2) and the b (4)D(1/2) levels have been measured and have the following values, tau = 0.75 +/- 0.10 s and tau = 0.54 +/- 0.03 s respectively. Furthermore, we have determined the transition probabilities for two forbidden transitions of a (4)F(7/2,9/2)-a (4)G(11/2) at 4243.97 and 4346.85 angstrom. Both the lifetimes and the transition probabilities are compared to calculated values in the literature.

Keyword
atomic data, methods: laboratory, techniques: spectroscopic, stars: individual: Eta Carinae
National Category
Atom and Molecular Physics and Optics Astronomy, Astrophysics and Cosmology
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-32215 (URN)10.1051/0004-6361/200913233 (DOI)000272417700054 ()
Available from: 2009-12-07 Created: 2009-12-07 Last updated: 2017-12-12Bibliographically approved
9. The FERRUM project: Laboratory-measured transition probabilities for Cr II
Open this publication in new window or tab >>The FERRUM project: Laboratory-measured transition probabilities for Cr II
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2010 (English)In: Astronomy and Astrophysics, ISSN 0004-6361, E-ISSN 1432-0746, Vol. 511, no A68Article in journal (Refereed) Published
Abstract [en]

Aims: We measure transition probabilities for Cr II transitions from the z ^4H_J, z ^2D_J, y ^4F_J, and y ^4G_J levels in the energy range 63000 to 68000 cm^{-1}.

Methods:Radiative lifetimes were measured using time-resolved laser-induced fluorescence from a laser-produced plasma. In addition, branching fractions were   determined from intensity-calibrated spectra recorded with a UV Fourier transform spectrometer. The branching fractions and radiative lifetimes were combined   to yield accurate transition probabilities and oscillator strengths.

Results: We present laboratory measured transition probabilities for 145 Cr II lines and radiative lifetimes for 14 Cr II levels. The laboratory-measured   transition probabilities are compared to the values from semi-empirical calculations and laboratory measurements in the literature.

Keyword
atomic data, line: identification, methods: laboratory, techniques: spectroscopic
National Category
Atom and Molecular Physics and Optics
Research subject
Physics
Identifiers
urn:nbn:se:su:diva-35978 (URN)10.1051/0004-6361/200913672 (DOI)000275752400094 ()
Available from: 2010-01-21 Created: 2010-01-21 Last updated: 2017-12-12Bibliographically approved

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