Bis(μ3-iodo)-pentakis(μ2-iodo)-penta-copper(I) e: A fully ordered, isolated [Cu5I7]2 cluster
2011 (English)In: Solid State Sciences, ISSN 1293-2558, Vol. 13, no 4, 768-772 p.Article in journal (Refereed) Published
Two new compounds, [(C4H9)4P]2[Cu5I7] and [(C4H9)4P]2[Cu5I7]·CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7]2− cluster. It displays a molecular symmetry very close to C2. Both compounds crystallize in space group P21/c.
Place, publisher, year, edition, pages
2011. Vol. 13, no 4, 768-772 p.
copper (I) iodide cluster structure
Research subject Materials Chemistry
IdentifiersURN: urn:nbn:se:su:diva-42782DOI: 10.1016/j.solidstatesciences.2010.03.019ISI: 000289965900014OAI: oai:DiVA.org:su-42782DiVA: diva2:351438