Dual graphs realized in the compounds di-μ3-4-mercaptopyridine catena-di-μ2-iodo-di-μ3-iodo-μ4-iodo penta copper(I) and di-μ3-4-mercaptopyridine-di-catena-iodo-di-μ3-iodo tri copper(I)
2010 (English)In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 183, no 11, 2656-2661 p.Article in journal (Refereed) Published
Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group I41/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide.
Place, publisher, year, edition, pages
2010. Vol. 183, no 11, 2656-2661 p.
copper iodide cluster structure
Research subject Materials Chemistry
IdentifiersURN: urn:nbn:se:su:diva-42785DOI: 10.1016/j.jssc.2010.09.009ISI: 000284179800023OAI: oai:DiVA.org:su-42785DiVA: diva2:351443