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The Crystal Structure of SrNb4O6
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
1995 (English)In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 114, 301-307 p.Article in journal (Refereed) Published
Abstract [en]

Single crystals of SrNb4O6 were obtained by heat treatment of a pelleted mixture of Sr5Nb4O15, Nb2O5, and Nb at 1670 degrees C in sealed Nb tubes. High-resolution electron microscopy (HREM) studies showed the structure to be an intergrowth of alternating slabs of SrNbO3 (perovskite-type structure) and NbO (ordered deficient NaCl-type structure), both two unit cells wide. SrNb4O6 has a tetragonal unit cell with a = 4.1655(3) Angstrom and c = 16.223(1) Angstrom and space group P4/mmm, Z = 2. The structure model obtained from the HREM images was refined, using single-crystal diffraction data, to R(f) = 3.0%

Place, publisher, year, edition, pages
1995. Vol. 114, 301-307 p.
National Category
Other Basic Medicine
Research subject
Materials Chemistry; Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-43901DOI: 10.1006/jssc.1995.1047OAI: oai:DiVA.org:su-43901DiVA: diva2:359767
Available from: 2010-10-29 Created: 2010-10-29 Last updated: 2017-12-12Bibliographically approved

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