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Enantioselective synthesis of (R)-bufuralol via dynamic kinetic resolution in the key step
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2010 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 75, no 13, 4596-4599 p.Article in journal (Refereed) Published
Abstract [en]

An enantioselective synthesis of (R)-bufuralol via a ruthenium- and enzyme-catalyzed dynamic kinetic resolution (DKR) has been achieved. The synthesis starts from readily available 2-ethylphenol and provides (R)-bufuralol in high ee and a good overall yield of 31%.

Place, publisher, year, edition, pages
American Chemical Society , 2010. Vol. 75, no 13, 4596-4599 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-45953DOI: 10.1021/jo100936fOAI: oai:DiVA.org:su-45953DiVA: diva2:370552
Funder
Knut and Alice Wallenberg FoundationSwedish Research Council
Note
3 Available from: 2010-11-17 Created: 2010-11-17 Last updated: 2017-12-12Bibliographically approved

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