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Perovskite-Type Ca1−xSrxNbO3(0≤x≤1) Phases: a synthesis, structure, and electron microscopy study
Moscow State University, Department of Chemistry.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Moscow State University, Department of Chemistry.
KTH.
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1998 (English)In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 141, 514-521 p.Article in journal (Refereed) Published
Abstract [en]

Reduced niobates Ca1−xSrxNbO3(0≤x≤1) with perovskite-type structures have been synthesized at 1500°C in niobium ampoules sealed under argon gas. The prepared compounds were characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and energy-dispersive X-ray analysis. The structure of CaNbO3(GdFeO3type) was refined using X-ray powder diffraction data. Electron diffraction studies showed that complex superstructures of the perovskite-type structure occur forx>0 in Ca1−xSrxNbO3: (i) forx=0.2 and 0.3 reflections corresponding to a supercell witha≈2×√2×aper,b≈4×aper, andc≈2×√2×aper(per=ideal perovskite) were observed, (ii) forx=0.5, 0.6, and 0.7 a cubic supercell was found witha=4×aper, whereas (iii) forx=0.8 and 0.9 the supercell is probably orthorhombic withac≈√2×aperandb≈2×aper. Forx=1.0 a new orthorhombic modification of SrNbO3withac≈√2×aperandb≈2×aperwas found. Resistivity measurements showed CaNbO3to have a nonmetallic type of conductivity, whereas the Sr-containing samples were metallic.

Place, publisher, year, edition, pages
1998. Vol. 141, 514-521 p.
National Category
Materials Chemistry
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-43885DOI: 10.1006/jssc.1998.8007OAI: oai:DiVA.org:su-43885DiVA: diva2:371569
Available from: 2010-11-21 Created: 2010-10-29 Last updated: 2017-12-12Bibliographically approved

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