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The effect of temperature on the pulsed current processing behaviour and structural characteristics of porous ZSM-5 and zeolite Y monoliths
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
2010 (English)In: Journal of the European Ceramic Society, ISSN 0955-2219, E-ISSN 1873-619X, Vol. 30, no 14, 2977-2983 p.Article in journal (Refereed) Published
Abstract [en]

Hierachically porous monoliths of ZSM-5 and Y zeolites have been prepared by pulsed current processing (PCP). The densification behaviour andstructural characteristics during rapid thermal treatment of the zeolites have been determined and related to the influence of the Si:Al ratio on thethermal stability of the zeolites. Monoliths of macroscopic shape can be prepared with an insignificant loss of surface area and micropore volumewhen the PCP-treatment was performed at temperatures below a critical maximum PCP temperature (TPCP). Full-profile fittings of the powderX-ray diffraction patterns showed that the lattice strain of zeolite Y increases rapidly above the critical TPCP while the ZSM-5 zeolites undergo aphase transition from orthorhombic to monoclinic. The use of a novel ceramic processing route for the production of the zeolite monoliths that donot significantly influence the structural characteristics and surface area of the starting materials has a potential to be of importance in catalysisand gas separation applications.

Place, publisher, year, edition, pages
2010. Vol. 30, no 14, 2977-2983 p.
Keyword [en]
Pulsed current processing; Porosity; X-ray methods
National Category
Inorganic Chemistry
Research subject
Materials Chemistry
Identifiers
URN: urn:nbn:se:su:diva-46202DOI: 10.1016/j.jeurceramsoc.2010.02.007OAI: oai:DiVA.org:su-46202DiVA: diva2:372055
Projects
Berzelii centre EXSELENT
Funder
Swedish Research Council
Available from: 2010-11-26 Created: 2010-11-23 Last updated: 2017-12-12Bibliographically approved
In thesis
1. Processing and performance of zeolites for efficient carbon dioxide separation
Open this publication in new window or tab >>Processing and performance of zeolites for efficient carbon dioxide separation
2015 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

We have structured zeolites from powders of zeolite 13X and 4A into hierarchically porous monoliths for efficient carbon dioxide capture by tailoring the pore dimensions to facilitate rapid gas uptake and release. Freeze-casting was used for the first time to shape adsorbents into a lamellar structure. Lamellar walls with thicknesses and spacing in the range of 10 µm were found to be the best combination between rapid gas transport and a short diffusion distance in the zeolite-containing walls for rapid carbon dioxide uptake and release.

Compressive strength measurements of the freeze-cast zeolite-based monoliths showed that monoliths with small pores, thin walls and a lot of interconnectivity between the walls were stronger than monoliths with large pores and thick walls. Image analysis of the structures together with modelling of the deformation behavior suggests that the failure mechanism of freeze-cast monoliths is dominated by buckling.

Binder-free zeolite Y and ZSM-5 -based monoliths were produced by pulsed current processing (PCP) into strong, hierarchically porous monoliths with minimal loss of crystallinity. Ranges for the maximum PCP processing temperatures for the zeolites with different aluminium contents were identified by powder x-ray diffraction (PXRD) with full-profile fitting analysis.

Matching the thermal expansion behavior of the supports with the zeolite film is important to minimize the risk of thermally induced cracking of zeolite membranes. Zeolite supports with a macroporous structure was prepared by PCP and the thermal expansion coefficient was determined by PXRD and compared to traditional alumina substrates. It was found that the slightly negative thermal expansion coefficient of the zeolite supports matched the thermal expansion of the zeolite films very well, whereas the alumina support would induce large stresses upon fluctuating temperatures.

Methylcellulose-directed synthesis of zeolite 4A produced nano-sized crystals with a narrow size distribution, which could be tuned by adjusting the methylcellulose content. The crystallinity of the synthesized 4A was controlled by PXRD and found to be very high, and the gas uptake capability performed well in comparison with available micron-sized zeolites.

Place, publisher, year, edition, pages
Stockholm: Department of Materials and Environmental Chemistry, Stockholm University, 2015. 69 p.
National Category
Materials Chemistry
Research subject
Materials Chemistry
Identifiers
urn:nbn:se:su:diva-114160 (URN)978-91-7649-107-2 (ISBN)
Public defence
2015-03-27, Magnéli Hall, Arrhenius Laboratory, Svante Arrhenius Väg 16 B, Stockholm, 13:00 (English)
Opponent
Supervisors
Funder
Berzelii Centre EXSELENT
Note

At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 2: Submitted.

Available from: 2015-03-05 Created: 2015-02-23 Last updated: 2015-12-02Bibliographically approved

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