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Chemoenzymatic dynamic kinetic resolution of axially chiral allenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2010 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, no 15, 4447-4451 p.Article in journal (Refereed) Published
Abstract [en]

Dimeric palladium bromide complexes bearing monodentate N-heterocyclic carbene ligands have been identified as efficient catalysts for the chemoselective racemization of axially chiral allenyl alcohols. In combination with porcine pancreatic lipase as biocatalyst, a dynamic kinetic resolution has been developed, giving access to optically active allenes in good yield and high enantiomeric purity (

Place, publisher, year, edition, pages
Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA , 2010. Vol. 16, no 15, 4447-4451 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-47404DOI: 10.1002/chem.201000301OAI: oai:DiVA.org:su-47404DiVA: diva2:373947
Funder
Swedish Research CouncilEU, FP7, Seventh Framework ProgrammeKnut and Alice Wallenberg Foundation
Note
3Available from: 2010-12-02 Created: 2010-12-02 Last updated: 2017-12-12Bibliographically approved

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