Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands
2010 (English)In: Organic and biomolecular chemistry, ISSN 1477-0520, E-ISSN 1477-0539, Vol. 8, no 20, 4536-4539 p.Article in journal (Refereed) Published
Active and selective catalysts for the asymmetric reduction of ketones, under transfer hydrogenation conditions, were obtained by combining [RhCl2Cp*](2), with a series of L-amino acid thioamide ligands functionalized with 1,2,3-triazoles. The obtained secondary alcohol products were formed with up to 93% ee.
Place, publisher, year, edition, pages
Royal Society of Chemistry , 2010. Vol. 8, no 20, 4536-4539 p.
IdentifiersURN: urn:nbn:se:su:diva-49133DOI: 10.1039/c0ob00400fISI: 000282315900009OAI: oai:DiVA.org:su-49133DiVA: diva2:376387
FunderSwedish Research CouncilKnut and Alice Wallenberg Foundation
authorCount :22010-12-102010-12-102011-01-17Bibliographically approved