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One-pot highly enantioselective catalytic Mannich-type reactions between aldehydes and stable α-amido sulfones: asymmetric synthesis of β-amino aldehydes and β-amino acids
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2010 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 51, no 2, 234-237 p.Article in journal (Refereed) Published
Abstract [en]

A highly enantioselective catalytic route to carbamate- and benzoate-protected beta-amino aldehydes and beta-amino acids is presented. The amino acid-catalyzed one-pot asymmetric reaction between unmodified aldehydes and alpha-amido sulfones gives the corresponding beta-amino compounds with up to 95:5 dr and 97-99%

Place, publisher, year, edition, pages
Elsevier Ltd , 2010. Vol. 51, no 2, 234-237 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-49636DOI: 10.1016/j.tetlet.2009.10.130ISI: 000274376300002OAI: oai:DiVA.org:su-49636DiVA: diva2:378768
Funder
Swedish Research Council
Note
authorCount :7Available from: 2010-12-16 Created: 2010-12-16 Last updated: 2017-12-11Bibliographically approved

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Deiana, LucaZhao, Gui-LingDziedzik, PawelCórdova, Armando
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