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Heterogeneous "organoclick" derivatization of polysaccharides: Photochemical thiol-ene click modification of solid cellulose
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2010 (English)In: Macromolecular rapid communications, ISSN 1022-1336, E-ISSN 1521-3927, Vol. 31, no 8, 740-744 p.Article in journal (Refereed) Published
Abstract [en]

A simple and direct method for derivatization of solid polysaccharides is presented. The novel methodology is based on the combination of organic acid-catalyzed esterification or etherification and photochemical thiol-ene click derivatization of a heterogeneous polysaccharide. The solid cellulose was “organoclick” modified with aryl, alkyl and polyester groups, respectively. The modification allows for a highly modular and metal free surface modification of solid polysaccharides.

Place, publisher, year, edition, pages
2010. Vol. 31, no 8, 740-744 p.
Keyword [en]
catalysis, cellulose, functionalization of polymers, polysaccharides, synthesis
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-50331DOI: 10.1002/marc.200900764OAI: oai:DiVA.org:su-50331DiVA: diva2:380778
Funder
Swedish Research Council
Available from: 2010-12-22 Created: 2010-12-22 Last updated: 2017-12-11Bibliographically approved

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Zhao, Gui-LingDeiana, LucaCórdova, Armando
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