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Resolution of Conformationally Chiral mer-[Ru(dqp)2]2+ and Crystallographic Analysis of [δ,δ-Ru(dqp)2][Δ-TRISPHAT]2 (dqp=2,6-Di(quinolin-8-yl)pyridine; TRISPHAT=Tris(tetrachlorocatecholate)phosphate)
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
2010 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, no 24, 7078-7081 p.Article in journal (Refereed) Published
Abstract [en]

Resolving the problem! The conformationally chiral bistridentate [Ru(dqp)2]2+ complex (dqp=2,6-di(quinolin-8-yl)pyridine) was resolved by selective precipitation using [Δ-TRISPHAT] (tris(tetrachlorocatecholate)phosphate) as the chiral auxiliary. The X-ray crystal structure of one diastereomer has been solved (see picture). No evidence for racemization was observed either at elevated temperature or with visible light.

Place, publisher, year, edition, pages
2010. Vol. 16, no 24, 7078-7081 p.
Keyword [en]
chiral resolution, conformational isomerism, N ligands, ruthenium
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-50649DOI: 10.1002/chem.201000570ISI: 000279856300003OAI: oai:DiVA.org:su-50649DiVA: diva2:383254
Note
authorCount :4Available from: 2011-01-04 Created: 2010-12-30 Last updated: 2017-12-11Bibliographically approved

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