Luminescence properties of monoclinic Cu4I4(Piperidine)4
2011 (English)In: Materials research bulletin, ISSN 0025-5408, E-ISSN 1873-4227, Vol. 46, no 8, 1192-1196 p.Article in journal (Refereed) Published
A new modification of Cu4I4Pip4 has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu4I4Pip4, the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission.
Place, publisher, year, edition, pages
Elsevier Ltd. , 2011. Vol. 46, no 8, 1192-1196 p.
Research subject Materials Chemistry
IdentifiersURN: urn:nbn:se:su:diva-55013DOI: 10.1016/j.materresbull.2011.04.012ISI: 000292722900007OAI: oai:DiVA.org:su-55013DiVA: diva2:400018