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A New Compound in the Cu-In System: the Synthesis and Structures of Cu10In7
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Inorganic Chemistry.
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Inorganic Chemistry.
2008 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 634, no 14, 2589-2593 p.Article in journal (Refereed) Published
Abstract [en]

A new binary phase, Cu10In7, was found during the investigation of the eta-phase field in the Cu-In system. Single crystals Cu10In7 were grown from a melt under an inert atmosphere. The compound crystallizes in the monoclinic space group C2/m with cell parameters a = 13.8453(2) angstrom, b = 11.8462(1) angstrom, c = 6.7388(1) angstrom and beta = 91.063(1). The structure is based on a unit of face-sharing octachedra consisting of five Cu4In2 octahedra terminated by Cu5In octahedra at both ends. The crystal Structure is closely related to the Cu11In9 structure type.

Place, publisher, year, edition, pages
2008. Vol. 634, no 14, 2589-2593 p.
Keyword [en]
Copper, Indium, Phase diagram, Crystal structure
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-57692DOI: 10.1002/zaac.200800275ISI: 000261236900023OAI: oai:DiVA.org:su-57692DiVA: diva2:417280
Note
authorCount :2Available from: 2011-05-16 Created: 2011-05-16 Last updated: 2017-12-11Bibliographically approved

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