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Synthesis and Crystal Structure of Ca2Ag1.83Al0.67Ge1.50: A Solid Solution with the NbCoB-type structure
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Inorganic Chemistry.
Stockholm University, Faculty of Science, Department of Physical, Inorganic and Structural Chemistry, Inorganic Chemistry.
2009 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 635, no 13-14, 2143-2146 p.Article in journal (Refereed) Published
Abstract [en]

The crystal structure of the new phase, Ca2Ag1.83Al0.67Ge1.50 (1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) angstrom, b = 4.3807(2) angstrom, c = 7.2211(3) angstrom, V = 648.65 angstrom(3) (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg2 (or CeCu2) and Fe2P type structures.

Place, publisher, year, edition, pages
2009. Vol. 635, no 13-14, 2143-2146 p.
Keyword [en]
Intermetallic phases, Solid solution, Intergrowth structure, X-ray diffraction, Silver
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-59388DOI: 10.1002/zaac.200900156ISI: 000272341200009OAI: oai:DiVA.org:su-59388DiVA: diva2:428959
Note
authorCount :2Available from: 2011-07-01 Created: 2011-06-27 Last updated: 2017-12-11Bibliographically approved

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