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Metal-free synthesis of aryl esters from carboxylic acids and diaryliodonium salts
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2011 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 13, no 13, 3462-3465 p.Article in journal (Refereed) Published
Abstract [en]

An efficient arylation of carboxylic acids with diaryliodonium salts has been developed, giving aryl esters in high yields within short reaction times for both arom. and aliph. substrates. The transition-metal-free conditions are compatible with a range of functional groups, and good chemoselectivity is obsd. with unsym. diaryliodonium salts.  Furthermore, steric hindrance in the ortho positions is well tolerated both in the carboxylic acid and in the diaryliodonium salt, yielding aryl esters that cannot be obtained via other esterification protocols.

Place, publisher, year, edition, pages
2011. Vol. 13, no 13, 3462-3465 p.
National Category
Organic Chemistry
Research subject
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-59894DOI: 10.1021/ol2012082ISI: 000291920800045OAI: oai:DiVA.org:su-59894DiVA: diva2:431829
Funder
Carl Tryggers foundation , 08:288Carl Tryggers foundation , 09:281Swedish Research Council, 621-2008-3709
Available from: 2011-07-26 Created: 2011-07-26 Last updated: 2017-12-08Bibliographically approved

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