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Investigation into the vibrational yield of OH products in the OH plus H plus H channel arising from the dissociative recombination of H3O+
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
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2009 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 130, no 21, 214302- p.Article in journal (Refereed) Published
Abstract [en]

The vibrational population of the hydroxyl radical, OH, formed in the OH+H+H channel arising from the dissociative recombination of the hydronium ion, H3O+, has been investigated at the storage ring CRYRING using a position-sensitive imaging detector. Analysis shows that the OH fragments are predominantly produced in the v=0 and v=1 states with almost equal probabilities. This observation is in disagreement with earlier FALP experiments, which reported OH(v=0) as the dominant product. Possible explanations for this difference are discussed.

Place, publisher, year, edition, pages
2009. Vol. 130, no 21, 214302- p.
Keyword [en]
dissociation, free radicals, hydrogen compounds, ion recombination, oxygen compounds, positive ions, vibrational states
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-60084DOI: 10.1063/1.3141434ISI: 000266674400016OAI: oai:DiVA.org:su-60084DiVA: diva2:432923
Note
authorCount :11Available from: 2011-08-08 Created: 2011-08-08 Last updated: 2017-12-08Bibliographically approved

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Zhaunerchyk, VitaliGeppert, Wolf D.Vigren, Erikaf Ugglas, MagnusLarsson, MatsThomas, Richard D.
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